Thermochemistry: determining the heat of reaction

Objectives

1. To determine the value of heat capacity of a calorimeter.

2.  To determine the heat of neutralization of HCl and NaOH.

Introduction

The Study of energy changes which take place during a chemical reaction is called thermochemistry or chemical energetic. Every chemical changes are accompanied by the evolution or absorption of heat, although in many cases this is not obvious as the amount is so small that no noticeable change in temperature occurs.
The heat can be measure by using calorimeter.
1.     The rises in temperature when a substance is heated depend on the heat capacity of the substance.
2.    The molar heat capacity of a substance is the energy required to raise the temperature of one mole of the substance by one kelvin.
3.    The specific heat capacity of a substance is the energy required to raise the temperature of 1 gram of the substance by one kelvin. For example, the specific heat capacity for water is 4.18 J g-1 K-1. This means that to raise 1g of water from T K to (T + 1) K requires 4.18 J of heat energy.
4.    The enthalpy change of reaction involving solutions can be calculated by the following equation

H = mc  T

Where   H = heat absorbed or liberated

C = Specific heat capacity

M = mass of solution

 T = the increase or decrease in temperature

Equipment
#     Stop watch
#     Calorimeter
#     Conical flask
#    Thermometer
#    100 ml beaker
#    Measuring cylinder
#    Bunsen burner

Reagent
 #  NaOH 1.0 M
# HCl 1.0 M
 # Distilled Water

Procedure

A.    

Determination of the heat capacity of a calorimeter

1.    The temperature of an empty calorimeter was measured by putting a thermometer inside the calorimeter, T1

2.    50 ml of distilled water poured into 100ml beaker.

3.    The beaker was heated to a temperature between 50°C to 60°C.

4.    Hot water poured into the calorimeter. The initial temperature of the hot water was taken immediately, T2.

5.    The decrease in temperature observed until it stays constant for a few minutes. The temperature was recorded, T3.


 Determination of the heat neutralization of HCl 1.0 M and NaOH 1.0M

1.    25 ml NaOH 1.0M and 25 ml HCl 1.0M was measured by using measuring cylinder.

2.    The NaOH Solution was poured into the calorimeter and the HCl solution into a conical flask. Record the initial temperature of each solution.

3.    Without removing the thermometer, the cover was lifted slightly and quickly poured all the HCl solution into the calorimeter.

4.    The cover of the calorimeter was quickly replaced.

5.    The solution was stirred and begun record the temperature every 15 seconds for 2 minutes.

6.    The experiment was repeated twice.

Result

A)   Determination of the heat capacity of a calorimeter

i)              T1 = 29°C

ii)             T2 = 64°C

iii)            T3 = 53°C

B)   Determination of the heat of neutralization of HCl 1.0M and NaOH 1.0M.

First experiment

Initial temperature of NaOH = 28°C

            Initial temperature of HCl = 28°C

Time(s)	Temperature(°C)
15	35
30	34
45	34
60	34
75	34
90	34
105	34
120	34

Table of NaOH + HCl for 2 minutes

Second Experiment

Initial temperature of NaOH = 28°C

            Initial temperature of HCl = 28°C

Time(s)	Temperature(°C)
15	35
30	34
45	34
60	34
75	34
90	34
105	34
120	34

Table of NaOH + HCl for 2 minutes

Charles’ Law

Objectives

To observe the effect of temperature on gas volume

Introduction

Charles's law states that at constant temperature, the volume of a fixed mass of gas is directly proportional to its absolute temperature. The mathematical expression of Charles’ law is as follows

 v inversely proportional to t( T = 273 + t ºc)

Or

          

  Charles’ law can be represented graphically by plotting the volume of a given gas against temperature. On extrapolation, the graph cuts the temperature at -273 ºC. This temperature is called absolute zero and was adopted as the zero on the kelvin scale or the absolute temperature scale.

Equipment

·        # Watch

·         #Erlenmeyer Flask with stopper

·         #500 ml tube

·         #Rubber stopper and clip

·         #Tripod stand

·         #Thermometer

·         #Bunsen burner

Reagent

-Nil-

Procedure

1.    1. The erlermeyer flask was weighed with the rubber stopper and its clip.

2.    2. Erlenmeyer flask was placed in the beaker with water.

3.    3. The water was boiled at least for 10 minutes without stopper so that the air inside the flask will have same temperature with the water boiling point.

4.    4. Sink was filled with water.

5.    5. Finished heating the flask, the end of the rubber tube was clip and marked.

6.    6. The flask removed from the boiling water and then the end of the tube was soaked together with the clip. Flask was leave in open air.

7.    7. The flask was unclipped to allow the water to get in. The air inside the flask reach the water temperature. Then flask was soaked again in the sink.

8.    8. The tube was clipped again at respective mark and removed from the sink.

9.    The reading at the air pressure meter was noted down.

Result

a)    Flask mass + assembles = 124.44 g

b)    Flask mass + assembles + inhaled water = 125.74 g

c)    Flask mass + assembles + water(full flask) = 248.2 g

Data elaboration

a)    Full flask water mass = 248.2 g

b)    Inhaled water mass = 1.3 g

c)    Inhaled water volume = 1.3 g

d)    Air volume at 100°C

= full flask water volume

= (a) / water density

= 248.2 g

e)    Air volume at room temperature :

= flask air volume at 100°C – inhaled water volume

= (d) – (c)

= 246.9 g

Question

1.    At What temperature, the calibration line cut the temperature axis. Compare with the theoretical value.

In theory, the temperature cut the axis at -273°C and this is called absolute zero.

2.    By using the Charles’ law and gas volume at 100ºC from your experiment, calculate the theoretical volume at the water in the sink temperature

Charles’ law

248 g                    =          V2

(100 + 273) k              (29+273)K

Therefore, V2 = 200.7 g

DETERMINATION OF THE FORMULA UNIT OF A COMPOUND

Determination of the formula unit of a compound

Objectives
1. To synthesis a zinc chloride compound.
2. To determine the formula unit of zinc chloride.


Introduction
Chemical compound is a pure chemical substance consisting of two or more different chemical elements which can be separated into simpler substances by chemical reaction chemical compound has a unique chemical structure and defined. They consist of the fixed ratio of atoms are held together in a room setting is defined by chemical bonds. Chemical compound molecule compounds that can be held together by covalent bonds, salt is held together by ionic bonds, intermetallic compounds are held together by metal ties, or a complex held together by a coordinate covalent bond. Another main property of a compound is its chemical composition, which identified only by determining the elements present in the compound. The calculation of the chemical composition of straight ahead. The molecular weight of the empirical formula weight divided by the number of atoms of each element to produce a percentage of each element. This is done for each element in the empirical formula and tabulated as chemical composition. Please note the order is based on electro-negative elements.



Equipment
#Glass Rod
#Crucible
#Wire Gauze
#Tripod Stand
#Porcelain tiles
#Analytical balance
#Bunsen Burner
#10ml of measuring cylinder

Reagent
#HCl 6.0 M
#Zinc Powder

Procedure
1. The crucible was weigh and the exact mass was recorded
2. Approximately 0.25g Zinc Powder was placed in the crucible. The Crucible was weigh again with it’s contain and the exact mass of the zinc powder is determined.
3. 10 ml of 6.0 M HCl solution is added into the crucible containing the zinc powder and the content was stir carefully using glass rod. A vigorous chemical reaction occurs and hydrogen gas was released.
4. Another 5 ml of 6.0 HCl solution was added until the zinc powder dissolve completely.
5. The crucible was placed on a hot plate in the fume cupboard and the heated slowly so that the compound not splatters during heating process.
6. The compound was heated until it completely dry.
7. The crucible was allowed to cool in room temperature, and then weigh it.
8. The crucible was reheat, let it cool at room temperature and then weighs again.
9. The process was repeat 3-4 times until the difference in mass is not more that 0.02 g.
10. The final mass of zinc chloride was determined from the final weigh of the sample. The mass of chlorine in the zinc chloride was calculated.
11. When the mass of zinc and chlorine obtained, the formula unit of zinc chloride is calculated.


Result

Materials                              Mass(g)  
Crucible                              51.92  
Crucible + Zinc Powder      52.18  
Zinc Powder                      0.25

Weight of the crucible + zinc chloride at 1st heating = 52.38 g
Weight of the crucible + zinc chloride at 2nd heating =52.37
Weight of the crucible + zinc chloride at 3rd heating =52.35

Emperical Formula

Element                              Zn                                 Cl  
Mass (g)                             0.25                                0.196  
No of Mole        0.25 / 65 = 0.00385           0.196 / 35 = 0.0056  
Ratio                               1                                  1.5  
Emperical Formula               2                                         3





Question

1. Explain why the content is not weighed while it is still hot?
It is always poor laboratory procedure to weigh something when it is still hot because the hot object will radiate heat in the form of convection currents in the air above the scale. This will alter the air pressure above the object unpredictably and produce unstable readings of the object being massed.

2. Compare the calculated formula unit with the theoretical formula unit. Explain why there is a difference and suggest ways to overcome the error.
The theorecal formula unit will be 1 Zn and 2 Cl so the theoretical formula unit is ZnCl2. But the calculated formula unit is 2 Zn and 3 Cl so the formula unit will be Zn2Cl3. There is a difference because the experiment was done in an open place where there is air presence and we weigh balance also not in a close condition, so there is some error. To overcome this error, the weigh balance should have its cover to prevent the air weighed too.

3. Based on your result, write the equation for the reaction between zinc and HCl.

Zn(s) + 2HCl(l)  H2(g) + ZnCl2





Reference

1. Success Chemistry SPM/Publisher:Oxford Fajar/Written by Tan Yin Toon, Loh Wai Leng and Tan On Tin
2. Ace Ahead stpm text Chemistry Volume 1/ Publisher: Oxford Tan Yin Toon, Loh Wai Leng and Kathirasan Muniandy

QUALITATIVE ANALYSIS OF CATIONS

Qualitative Analysis Of Cations

Objectives
Student can differentiate qualitatively a few cations in the lab

Introduction
Qualitative analysis is used to separate and detect cations and anions in a sample substance. there are several solutions containing ionic substances can be chemically analyzed to determine the presence of certain cations. Qualitative analysis based on the use of several chemical tests that can give a clear result for each specific cause of some ions in the solution. The reagent can react with a specific cation and observation of the reaction can be certified if the cation is known and there is no reaction means no specific cation or a cation can also be stated. The study was based on the determination of the ion is more than a few reagents.

Equipment
-Glass tube rack
-Glass Tube
-Dropper
-Self adhesive paper



Reagent

These solution with concentration of 0.1 M of

-Plumbum (II) nitrate, Pb(NO3)2
-Copper (II) Nitrate, Cu(NO3)2
-Iron (III) Nitrate, Fe(NO3)2
-Cobalt (II) Nitrate, Co(NO3)2
-Zinc (II) Nitrate, Zn(NO3)2
-Magenesium (II) Nitrate, Mg(NO3)2
-Barium (II) Nitrate, Ba(NO3)2
-Cation X
-Cation Y

#Sodium Sulphate Solution, Na2SO4, 2M
#Ammonium Sulphide Solution, (NH4)2S, 1M
#Sodium hydroxide solution, NaOH, 4M
#Ammonium tiocianate, NH4SCN, 2M


Procedure :
A) Reaction with sulphate ion, SO4²¯
1. 9 Glass tube was prepared and labeled with a until i
2. The glass tube was filled with 5 ml of distilled water
3. 10 drops of Plumbum (II) nitrate, Pb(NO3)2 solution is added into glass tube A, 10 drops of Copper (II) Nitrate, Cu(NO3)2 solution is added into glass tube b, 10 drops of Iron (III) Nitrate, Fe(NO3)2 solution is added into glass tube C, 10 drops of Cobalt (II) Nitrate, Co(NO3)2  solution is added into glass tube D, 10 drops of Zinc (II) Nitrate, Zn(NO3)2 solution is added into glass tube E, 10 drops of Magenesium (II) Nitrate, Mg(NO3)2 solution is added into glass tube F, 10 drops of Barium (II) Nitrate, Ba(NO3)2
solution is added into glass tube G, 10 drops of Cation X solution is added into glass tube H and 10 drops of Cation Y solution is added into glass tube I.
4. 10 drops of sodium sulphate solution was added in each glass tube and the tube is shaken after adding. Hold for 5 minutes.
5. Observation was recorded.

B) Reaction with suphide ion
1. 9 Glass tube was prepared and labeled with a until i
2. The glass tube was filled with 5 ml of distilled water
3. 10 drops of Plumbum (II) nitrate, Pb(NO3)2 solution is added into glass tube A, 10 drops of Copper (II) Nitrate, Cu(NO3)2 solution is added into glass tube b, 10 drops of Iron (III) Nitrate, Fe(NO3)2 solution is added into glass tube C, 10 drops of Cobalt (II) Nitrate, Co(NO3)2  solution is added into glass tube D, 10 drops of Zinc (II) Nitrate, Zn(NO3)2 solution is added into glass tube E, 10 drops of Magenesium (II) Nitrate, Mg(NO3)2 solution is added into glass tube F, 10 drops of Barium (II) Nitrate, Ba(NO3)2
solution is added into glass tube G, 10 drops of Cation X solution is added into glass tube H and 10 drops of Cation Y solution is added into glass tube I.
4. 10 drops of sodium sulphide solution was added in each glass tube and the tube is shaken after adding. Hold for 5 minutes.
5. Observation was recorded.

C) Reaction with thiocianate ion
1. 9 Glass tube was prepared and labeled with a until i
2. The glass tube was filled with 5 ml of distilled water
3. 10 drops of Plumbum (II) nitrate, Pb(NO3)2 solution is added into glass tube A, 10 drops of Copper (II) Nitrate, Cu(NO3)2 solution is added into glass tube b, 10 drops of Iron (III) Nitrate, Fe(NO3)2 solution is added into glass tube C, 10 drops of Cobalt (II) Nitrate, Co(NO3)2  solution is added into glass tube D, 10 drops of Zinc (II) Nitrate, Zn(NO3)2 solution is added into glass tube E, 10 drops of Magenesium (II) Nitrate, Mg(NO3)2 solution is added into glass tube F, 10 drops of Barium (II) Nitrate, Ba(NO3)2
solution is added into glass tube G, 10 drops of Cation X solution is added into glass tube H and 10 drops of Cation Y solution is added into glass tube I.
4. 10 drops of ammonium thiocianate solution was added in each glass tube and the tube is shaken after adding. Hold for 5 minutes.
5. Observation was recorded.

D) Reaction with hydroxide ion
1. 9 Glass tube was prepared and labeled with a until i
2. The glass tube was filled with 5 ml of distilled water
3. 10 drops of Plumbum (II) nitrate, Pb(NO3)2 solution is added into glass tube A, 10 drops of Copper (II) Nitrate, Cu(NO3)2 solution is added into glass tube b, 10 drops of Iron (III) Nitrate, Fe(NO3)2 solution is added into glass tube C, 10 drops of Cobalt (II) Nitrate, Co(NO3)2  solution is added into glass tube D, 10 drops of Zinc (II) Nitrate, Zn(NO3)2 solution is added into glass tube E, 10 drops of Magenesium (II) Nitrate, Mg(NO3)2 solution is added into glass tube F, 10 drops of Barium (II) Nitrate, Ba(NO3)2
solution is added into glass tube G, 10 drops of Cation X solution is added into glass tube H and 10 drops of Cation Y solution is added into glass tube I.
4. 10 drops of sodium hydroxide was added in each glass tube and the tube is shaken after adding. Hold for 5 minutes.
5. Observation was recorded.




Result
Suphate

Test Tube                 Observation                                         Equation  
A Cloudy solution with white precipitate (Na2SO4 + Pb(NO3)2  -----> PbSO4 + 2NaNO3) 
B Light Blue Cloudy Solution (Na2SO4  + Cu(NO3)2-----> CuSO4 + 2NaNO3)  
C Goldish solution with little orange precipate (Na2SO4 + Fe(NO3)2-----> FeSO4 + 2NaNO3)
D Clear solution (Na2SO4 + Co(NO3)2-----> CoSO4 + 2NaNO3)
E Cloudy solution with white precipitate (Na2SO4 + Zn(NO3)2-----> ZnSO4 + 2NaNO3 )  
F Clear Solution (Na2SO4 +  Mg(NO3)2-----> MgSO4 + 2NaNO3)  
H Cloudy solution with white precipitate (Na2SO4  +  Ba(NO3)2-----> BaSO4 + 2NaNO3)
G Cloudy solution with white precipitate  
I Clear Solution

Sulphide

Test Tube Observation                                         Equation  
A Brown solution with black precipitate  (NH4)2S + Pb(NO3)2-----> 2NH4NO3 + PbS   
B Light yellowish solution with black precipitate (NH4)2S + Cu(NO3)2-----> 2NH4NO3 + Cu  
C Black Solution (NH4)2S + Fe(NO3)2-----> 2NH4NO3 + FeS  
D Black Solution (NH4)2S + Co(NO3)2-----> 2NH4NO3 + CoS  
E Light brown solution with dark brown precipitate (NH4)2S +  Zn(NO3)2-----> 2NH4NO3 + ZnS  
F Colourless solution (NH4)2S +  Mg(NO3)2-----> 2NH4NO3 + MgS  
G Colourless Solution (NH4)2S +  Ba(NO3)2-----> 2NH4NO3 + BaS  
H Light brown solution with dark brown precipitate  
I Colourless solution with white precipitate

Hydroxide

Test Tube Observation Equation  
A Clear Solution 2NaOH + Pb(NO3)2-----> 2NaNO3 + Pb(OH)2  
B Colourless solution with dirty green precipitate 2NaOH + Cu(NO3)2-----> 2NaNO3 + Cu(OH) 
C Colourless solution with brown precipitate 2NaOH +  Fe(NO3)2-----> 2NaNO3 + Fe(OH)2  
D Colourless solution with brown precipitate 2NaOH +  Co(NO3)2-----> 2NaNO3 + Co(OH)2  
E Clear solution 2NaOH +  Zn(NO3)2-----> 2NaNO3 + Zn(OH)2  
F Cloudy 2NaOH +  Mg(NO3)2-----> 2NaNO3 + Mg(OH)2  
G Clear Solution 2NaOH +   Ba(NO3)2-----> 2NaNO3 + Ba(OH)2  
H Clear Solution  
I Clear Solution

Tiocianate

Test Tube Observation Equation  
A Clear Solution 2NH4SCN+  Pb(NO3)2----->2 NH4NO3 + PbSCN  
B Light Green 2NH4SCN +  Cu(NO3)2-----> 2 NH4NO3 + CuSCN  
C Dark brownish 2NH4SCN + Fe(NO3)2-----> 2 NH4NO3 + FeSCN  
D Light Pink  2NH4SCN+  Co(NO3)2-----> 2 NH4NO3 + CoSCN  
E Clear Solution 2NH4SCN +  Zn(NO3)2-----> 2 NH4NO3 + ZnSCN  
F Clear Solution 2NH4SCN +  Mg(NO3)2-----> 2 NH4NO3 + MgSCN  
G Clear Solution 2NH4SCN+   Ba(NO3)2-----> 2 NH4NO3 + BaSCN  
H Clear Solution  
I Clear Solution









Discussion
This experiment shows on how reagents can be used to produce colored solutions or precipitates when certain ions are present.  Using such techniques to determine what components are present in a sample is called qualitative analysis. The cations to be studied include some common alkali metals (Na+ and K+) and some alkaline earth metals (Mg2+, Ca2+, and Ba2+), along with Zn2+, Al3+, and NH4+.  These ions are not colored in solution, and most of their compounds are white.  It is impossible therefore to use colors of solutions or precipitates to indicate which of these cations is present in solution.  So, in this experiment, will use differences in solubilities to separate the cations from each other.  Na+, K+, and NH4+ ions form very few insoluble compounds. All the sulfates of the cations listed above are all soluble, with the exception of barium sulfate.  Calcium sulfate is slightly soluble and will not precipitate under the conditions of this experiment.  Thus adding sulfate to a mixture of these cations will allow to detect barium and remove it from solution. Four of the other cations form insoluble hydroxides. (Calcium hydroxide is slightly soluble, but will precipitate in a strongly basic solution.)  Two of these, however, are amphoteric and will dissolve in a strongly basic solution to form complex ion. By making the solution strongly basic, then, two of the remaining cations will precipitate, while two more will be converted to complex ions.  The two which precipitate can be separated due to differences in the solubilities of their oxalates.  One of them will precipitate when ammonium oxalate is added. The solution containing the complex ions will then be acidified, then neutralized with NH3(aq).  In this weakly basic solution one of the amphoteric hydroxides will precipitate, while the other forms a complex ion with NH3(aq).  Finally, this last cation is precipitated with sulfide ion.

Rindu dengan mereka berdua, insan teristimewa

Hari ini bday adik saya, tapi dia jau di sabah saaaaaaaaaaana, saya di shah alam. Tadi saya kol la diorang, and saya sangat-sangat jelesh, diorang dua ( ma mum n ma adeq) sedang excited mau buat persiapan untuk esok. diorang buat makan-makan. Panggang-panggang ayam. And so on. Huhu. Rindu dengan mereka berdua. oh, julai, come faster. Saya sudah x sabar balek sabah.

Oh My Mum

...

Dulu-dulu masa di sabah, saya suka gaduh dengan mai mum. Sebab, saya memang panas baran. tak boleh kena marah sikit. hehe. Saya akui 2. sebab tu la. saya kena tegur. sekarang saya da tak panas baran sangat. Saya rindu mai mum. walaupun dia suka membebel dari pagi. buka mata jak start da la dia 2. sebab, sampai saya form 6 pun masih kena paksa bangun tidur. memang biasa la 2. haha. alarm. sekarang nie, saya rindu dengar alarm mai mum tu. saya memang suka cakap-cakap dengan mai mum, pasal study, kawan and others. ngumpat dengan mai mum. suka la. Bila da jauh, saya selalu tepon dia. tapi rasa nya x puas la. yalah. kalau kol memang la sampai sejam. tapi kadang-kadang ada hal remeh-remeh mau cakap dengan dia tu. x dapat nak cakap. haiya. rindu dengan dia. Bila kol dia, kadang-kadang tu mesti dia dengan mai adeq gaduh. tapi apapun, i mish that moments. 

Oh my adeq

...

Dulu-dulu, bila saya di sabah, saya suka marah adeq saya, sebab saya suka marah-marah. eksen la, kan big sister. tapi kami dua b'ngam jugak. kami buat benda yang sot-sot bersama. and kami selalu buli mum saya. sampai sekarang dia xmau mengakui yang saya sudah 19. dia kata "adui moi, muka mu ni 19 tahun" .. hihi .. sebab 19teen selalu tengok orang da besar. =). Dia x pernah sebut nama saya betul walaupun dalam keadaan bergurau, dia akan panggil amoi jugak, even to her friends. Sweet little sister.

Dulu-dulu, saya suka suruh dia buat ini la, itu la, besa la, big sister ka. tunjuk kuasa sikit. sekarang nie, rindu mau suruh-suruh dia bila saya malas. tapi x dapat. I appreciate her.. =) .. Sayang mai adeq. Sekarang ni mai adeq da 17 tahun, besa da dia. Spm 2, tapi kadang saya rasa dia bukan form 5. sungguh cepat masa berlalu. Oh mai adeq.

I'll owez love you my mum n my adeq.

=)

Aku+Dia=Cuma Kawan

Banyak orang kata lelaki dan perempuan tak boleh jadi bestfriend. agaknya kenapa ya?

Mengikut pengalaman aku la kan, orang cakap cam 2 sebab selalu mereka ini mesti ends up sebagai couple. Apa yang membuat bestfriend ni cenderung jadi couple is

1. Bila kita ada masalah, dia akan sedia mendengar
2. Hanya dia yang tahu isi hati kita
3. Hanya dengan dia kita boleh bergurau tanpa rasa risau dia akan terasa
4. Dia tau bila kita bad mood and dia akan jaga hati kita
5. Walaupun kita marah dia, dia takkan simpan dalam hati
6. dan banyak lagi

Sebab faktor di atas 2 la kita rasa selesa ngan dia and kadang2 akan bandingkan dia ngan bf kita.
Aku cakap dari pengalaman la. Pernah lah hampir2. Tapi fikir jugak, kan kapel jadi kawan nanti macam lain. Nanti kalau gadu, akan terasa sangat sebab x da tempat mau luahkan.. =). hehe.

Untuk entry ni, ada 1 lagu yang betul2 sesuai
Auburn- Bestfriend


The thought of this is killing me, it's been on my mind .
Can't believe it's been right here after all this time .
And even though I love you I can't seem to find someone who cares the way you do
You know, I love the way we're always been nothing more than friends .
So why do I give every man the stand up .
Thought I was over this but once again I'm comparing you to him .
And I find that there's no you in him at matters


Boy even though your my bestfriend
I can't help it whenever I compare you to him
It's like I always do this
With every single man
And I hate that I can't find someone who's worth my time
Just like my bestfriend .

And I know you hear me say this all the time
I don't do relationships cause I'm on my grind.
But see your part of this
Because I just can't find someone who knows me like you do
Always brought out the good in me
Don't know just what you see,
Whatever it is, no other guy has even tried .
Remember when you left one day and turned around to say "your my bestfriend"
And right there you made me cry .


Even though your my bestfriend
I can't help it whenever I compare you to him
It's like I always do this
With every single man
And I hate that I can't find someone whos worth my time
Just like my bestfriend .

I'm trying to let you know
A part of me just can't let this go
Never had a friend, one who understands
with you it felt so free
I don't know whatchu did .
But I know whatever it is
I'm so thankful for you
I'm so grateful for you

Even though the things I told you .

Karak

Semalam aku,yaya and reen pegi nonton karak. Seram citer. Aku n yaya ngan aksi yang x boleh d terima menutup mata dengan tangan bila aksi seram 2 memang lawak. Haha. Cerita 2 best tapi endingnya membawa banyak persoalan. Kata Yaya, nanti ada Karak 2. Haha.
karak ni cerita dia cam nie, ## Empat pelajar kolej sedang menuju kembali ke Kuantan selepas bermalam di KL dan mereka terperangkap dalam kesesakan lalulintas yang teruk sepanjang Karak Highway.

Oleh kerana mereka mempunyai kelas pada keesokan awal paginya, mereka membuat keputusan untuk keluar dari lebuhraya dan meneruskan perjalanan mereka menggunakan jalan lama. Mereka tidak mengetahui bahawa keputusan ini akan mengubah hidup mereka selamanya.

Kisah sebuah kereta Volkswagen kuning yang dianggap berhantu, yang sering mengganggu perjalanan di sekitar lebuhraya Jelapang. Hantu Volkswagen kuning ini mula menganggu kenderaan di jalan raya sejak tahun 1956, tetapi tidak ketara dan orang ramai masih belum menganggap ia sesuatu yang mengaibkan.

Tetapi sejak lebuhraya Utara Selatan dibina merentasi kawasan yang dinamakan Jelapang, sejak itulah hantu Volkswagen kuning semakin ketara muncul dengan mengganggu kenderaan yang lalu lalang di situ. Puncanya dipercayai bermula dari sebuah kisah seorang isteri curang yang telah membunuh suaminya dengan kejam dan kemudian merampas kereta Volkswagen kuning milik suaminya.

Sang suami mati sambil menyimpan rasa dendam yang membara untuk memiliki semula Volkswagen kuning tersebut. Kenyataannya, jika benar hantu Volkswagen kuning ini wujud dan pernah dilihat orang, maka itu adalah jin (keturunan iblis yang bergelar jembalang), bukan si suami malang yang mati dibunuh kejam.

Volkswagen ini akan muncul secara tiba-tiba dan sekiranya pemandu memotong kereta tersebut , ia akan berada di hadapan secara mengejut.Dipercayai , kemalangan berlaku disebabkan gangguan Volkswagen kuning.##

Nanti ending dia kesian. Hihi.Kami sempat la snap2 gambar jugak. Sebab Kami pegi dalam jam 10 lebih. Beli tiket yang pukul  12.15. Habis jam 2 pagi. Sambil tunggu 2. kami lepak d kedai mamak. N pegi dalam jam 11.40 cam 2. Pas 2 sempat la snap2 dalam SP.